Advanced Potentiometry: Potentiometric Titrations and Their Systematic Errors by Erzsébet Néher-NeumannAdvanced Potentiometry: Potentiometric Titrations and Their Systematic Errors by Erzsébet Néher-Neumann

Advanced Potentiometry: Potentiometric Titrations and Their Systematic Errors

byErzsébet Néher-Neumann

Paperback | October 19, 2010

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This monograph features the calculation of the total potential anomalies/systematic errors in emf cells containing either mixtures of strong electrolytes or equilibrium systems at all the experimental conditions generally used in potetiometric titrations. A critical analysis of these methods is presented. At present, there are serious systematic errors in the calculation methods used at the interpretation of emf data, which result in erroneous suggestion of the complexes formed (often polynuclear which do not exist!).Why is this book needed?Potentiometry is a classical investigation method.  It is important that this method is correct, free from systematic errors and it that it describes both nature and the enviroment correctly.
Title:Advanced Potentiometry: Potentiometric Titrations and Their Systematic ErrorsFormat:PaperbackDimensions:370 pages, 9.25 × 6.1 × 0 inPublished:October 19, 2010Publisher:Springer NetherlandsLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:9048181488

ISBN - 13:9789048181483

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Table of Contents

Preface1. Introduction2. Emf cells with mixtures of strong electrolytes and liquid junctions of the type AY ¦ AY + HY + BYz(B)3. Determination of the ionic molar conductivities in mixtures of the strong electrolytes HClO4 + NaClO4 + Cd(ClO4)24. Studies on emf cells where complex formation takes place using liquid junctions of the type AY ¦ AY + HY + BYz(B) + AyL and - log10 [H+] 75. Estimation of the total potential anomalies and the determination of the equilibrium constants in emf cells where every kind of complex can be present6. On emf titrations proposed for the determination of some interaction coefficients7. Emf titrations proposed for the determination of certain transport numbers8. Studies on emf cells where strong complexes are formed using liquid junctions of the type AY ¦ AY + BYz(B) + HY + AyL at [Y-] = C M, constant, and - log10 [H+] 7