Efficient Methods For Preparing Silicon Compounds

Paperback | May 31, 2016

byHerbert W Roesky

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Efficient Methods for Preparing Silicon Compoundsis a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area.

Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry.



  • Includes contributions and edits from leading experts in the field
  • Includes detailed chemical schemes and useful references for each preparative method
  • Organized by the coordination numbers of the central silicon atom for each compound for easy navigation
  • Serves as a go-to primer for researchers in novel compositions of silicon matter

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From the Publisher

Efficient Methods for Preparing Silicon Compoundsis a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researcher...

From the Jacket

Efficient Methods for Preparing Silicon Compoundsis a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia as well as industry. Silicon is the second most abundant element in Earth's crust and is therefore ubiquitously available and used in every computer and ship due ...

Herbert W. Roesky is an Emeritus Professor for Inorganic and Organometallic Chemistry with a broad experience in materials chemistry, homogeneous catalysis, fluorine, aluminum, and silicon chemistry as well as chemical education. In the tradition of great European chemical lecture demonstrations, he has given experimental lectures all ...

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Format:PaperbackDimensions:538 pages, 8.75 × 6.35 × 0.68 inPublished:May 31, 2016Publisher:Academic PressLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0128035307

ISBN - 13:9780128035306

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Table of Contents

1. Preface 2. Preparation of the NHC (L1,2) and its Application for Synthesizing Lewis Base Stabilized Dichlorosilylene L1,2SiCl23. Lithium Tris(2,4,6-Triisopropylphenyl) Disilenide: A Versatile Reagent for the Transfer of the Disilenyl-Group 4. Preparation of a SiCS Three- and a SiO2C2Five-Membered Ring System 5. Cobalt-Methylidyne-Silanetriol as Precursor for Catalytic Hydroformylation in a Two-Phase System 6. Convenient and High Yield Access to Silicon(II) Compounds Using Alkali Metal Amides as Dehydrochlorinating Agents 7. From Bis-silylene to Cyclodisiloxane 8. From bis-silylene to 1,4-disilabenzene: An Efficient Method to Generate Silicon Analogue of Benzene 9. Silanetriols: Synthesis, Characterization, and Structures 10. From Silanetriols to Aluminosilicates 11. Synthesis of a Zwitter-Ionic 2,4-Disila-1,3-Diphosphacyclobutadiene Compound 12. Facile Synthesis Of Silaimine Complex Phc(Ntbu)2si(Cl)=N(2,6-Ipr2c6h3) 13. One Pot Synthesis ofE- [N(SiMe3)2](-1-Me5C5)Si=Si(-1-Me5C5)[N(SiMe3)2] 14. Access to Silicon(IV) Compounds with a Si-N Bond from Silicon(II) Precursors by N-H Bond Activation 15. Access to Silicon(IV) Compounds from Silicon(II) Precursors by C-H and C-F Bond Activation 16. Silylene as a Lewis Base with a Three-Coordinate Silicon 17. A Stable Silicon(II) Monohydride 18. Tetra(Silyl)Methane, (H3Si)4C, A Volatile Carbosilane for the Chemical Vapour Deposition of Amorphous Silicon Carbide Thin Films 19. Trimethylsilylperrhenate- A Non-Ionic Reagent Soluble in Organic Solvents for the Preparation of Perrhenates 20. (Monosodiumoxy)Organoalkoxysilanes (Rebrov Salts)- Polyfunctional Monomers For Silicone Syntheses 21. Hydrido Silyl Complexes of Chromium with Metal-Hydrogen-Silicon Three-Center Bonds