Fluoropolymers 2: Properties

Hardcover | November 30, 1999

EditorGareth G. Hougham, Patrick E. Cassidy, Ken Johns

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The fluorine atom, by virtue of its electronegativity, size and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme high-performance applications have found their way into our homes, our clothing and even our language. Much progress has been made in understanding the sometimes confounding properties of fluoropolymers. Computer simulation is now contributing to this with new fluorine force fields and other parameters, bringing realistic prediction within reach of the practicing physical chemist. Fluoropolymers 1: Synthesis and Fluoropolymers 2: Properties attempt to bring together in one place the chemistry, physics and engineering properties of fluoropolymers. The collection was intended to provide balance between breadth and depth, with contributions ranging from the introduction of fluoropolymer structure-property relationships, to reviews of subfields, to more focused topical reports.

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The fluorine atom, by virtue of its electronegativity, size and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals and surface modifiers are only a few examples. Fluoropol...

Format:HardcoverDimensions:425 pages, 9.21 × 6.14 × 0.04 inPublished:November 30, 1999Publisher:Springer USLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0306460610

ISBN - 13:9780306460616

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Table of Contents

Fluoropolymers 1: Synthesis: Preface; G.G. Hougham. I. Synthesis: 1. Polyacrylates containing the Hexafluoroisopropylidene Function in the Pendant Groups; V.S. Reddy, et al. 2. Fluorinated Cyanate Polymers; A. Snow, L. Buckley. 3. Polymers from the Thermal 2 pi+2 pi Cyclodimerization of Fluorinated Olefins; D. Babb. 4. Functional Fluromonomers and Fluoropolymers; Ming-H. Hung, et al. 5. Use of Original Fluorinated Telomers in the Synthesis of Hybrid Silicones; B. Ameduri, et al. 6. Chlorotrifluoroethylene Suspension Polymerization; M.H. Andrus Jr., et al. 7. Fluorinated Polymers with Functional Groups: Synthesis and Application. LB-Films from Functional Fluoropolymers; B.V. Mislavsky. 8. Synthesis of Fluorinated Poly(arylethers) containing 1,4-Naphthalene Moieties; F. Mercer, et al. 9. Synthesis and Properties of Fluorine-Containing Aromatic Condensation Polymers obtained from Bisphenol-A F and its Derivatives; S. Nakamura, Y. Nishimoto. 10. Novel Fluorinated Block Copolymers Synthesis and Application; S. Oestrich, M. Antonietti. 11. Synthesis and Structure-Property Relationships of Low-Dielectric-Constant Fluorinated Polyacrylates; H.S.W. Hu, J.R. Griffith. 12. Epoxy Networks from a Fluorodiimidediol; H.S.W. Hu, J.R. Griffith. 13. Synthesis of Fluoropolymers in Liquid and Supercritical Carbon Dioxide Solvent Systems; J.P. Young, et al. II. Direct Fluorination: 14. Direct Fluorination of Polymers; R.J. Lagow, Han-Chao Wei. 15. Surface Fluorination of Polymers Using Xenon Difluoride; G. Barsamian, V. B. Sokolov. 16. New Surface Fluorinated Products; P.A.B. Carstens, et al. 17. Modified Surface Properties of Technical Yarns; M. Weber, D. Shilo. III. Vapour Deposition: 18. Vapour Deposition Polymerization as a Route to Fluorinated Polymers; J.A. Moore,Chi-I Lang. 19. Ultrathin PTFE, PVDF, and FEP Coatings Deposited using Plasma-Assisted Physical Vapour Deposition; K.J. Lawson, J.R. Nicholls. Index Fluoropolymers 2: Properties: I. Processing, Structure and Properties. 1. A Perspective on Solid State Microstructure in Polytetrafluoroethylene; T. Davidson, et al. 2. Teflon AF: A Family of Amorphous Fluoropolymers with Extraordinary Properties; P. Resnick, W. Buck. 3. Supercritical Fluids for Coatings from Analysis to Xenon: A Brief Overview; K. Johns, G. Stead. 4. The Material Properties of Fluoropolymers and Perfluoroalkyl-Based Polymers; R. Thomas. 5. Excimer Laser-Induced Ablation of Doped Poly(tetrafluoroethylene); C. Davis, et al. 6. Novel Solvent and Dispersal Systems for Fluoropolymers and Silicones; M. Grenfell. 7. Fluoropolymer Alloys&endash;Performance Optimization of PVDF Alloy; S. Lin, K. Argasanski. 8. The Solubility of Poly(tetrafluoroethylene) and its Copolymers; W. Tuminello. 9. Structure-Property Relations based on Fluoropolyether Macromers Coatings; S. Turri, et al. II. Modeling and Simulation: 10. Molecular Modeling of Fluoropolymers: Fluorotetrafluroethylene; B.L. Farmer, et al. 11. Material Behavior of Poly(vinylidene fluoride) Deduced from Molecular Modeling; G. Rutledge, J.D. Carbeck. 12. Application of Chemical Graph Theory for the Estimation of the Dielectric Constant of Polymides; B. Sherman, V. Galiatsatos. III. Fluorine-Containig Polymides: 13. Fluorine Containing Polymides; G. Hougham. 14. Synthesis and Properties of Perfluorinated Polymides; S. Ando, et al 15. Synthesis and Properties of Partially Fluorinated Polymides for Optical Applications; T. Matsura, et al. 16. Novel organo-Soluble Fluorinated Polyimides for Optical, Microeletronic and Fiber Applications; F.W. Harris, et al. 17. Application of Fluorine-19 NMR Toward Chemistry of Imide Materials in Solution; C.D. Smith, et al.