Molecular Beam Epitaxy: A Short History

Hardcover | July 25, 2015

byJohn Orton, Tom Foxon

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Our book is a history of Molecular Beam Epitaxy (MBE) as applied to the growth of semiconductor thin films (note that we do not cover the subject of metal thin films). We begin by examining the origins of MBE, first of all looking at the nature of molecular beams and considering theirapplication to fundamental physics, to the development of nuclear magnetic resonance and to the invention of the microwave MASER. We show how molecular beams of silane (SiH4) were used to study the nucleation of silicon films on a silicon substrate and how such studies were extended to compoundsemiconductors such as GaAs. From such surface studies in ultra-high vacuum the technique developed into a method of growing high quality single crystal films of a wide range of semiconductors. We compare this with earlier evaporation methods of deposition and with other epitaxial deposition methodssuch as liquid phase and vapour phase epitaxy (LPE and VPE). We describe the development of MBE machines from the early "home-made" variety to that of commercial equipment and show how MBE was gradually refined to produce high quality films with atomic dimensions. This was much aided by the use of various in-situ surface analysis techniques, such asreflection high energy electron diffraction (RHEED) and mass spectrometry, a feature unique to MBE. We look at various modified versions of the basic MBE process, then proceed to describe their application to the growth of so-called "low-dimensional structures" (LDS) based on ultra-thinheterostructure films with thickness of order a few molecular monolayers. Further chapters cover the growth of a wide range of different compounds and describe their application to fundamental physics and to the fabrication of electronic and opto-electronic devices.We study the historical development of all these aspects and emphasise both the (often unexpected) manner of their discovery and development and the unique features which MBE brings to the growth of extremely complex structures with monolayer accuracy.

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Our book is a history of Molecular Beam Epitaxy (MBE) as applied to the growth of semiconductor thin films (note that we do not cover the subject of metal thin films). We begin by examining the origins of MBE, first of all looking at the nature of molecular beams and considering theirapplication to fundamental physics, to the developme...

John Orton won an Exhibition at Magdalen College, Oxford, where he obtained an honours degree in Physics, followed by a D Phil, with a thesis on Electron Spin Resonance in magnesium oxide. He joined Mullard (later Philips) Research Laboratories in 1960 to work on the development of the microwave maser. In 1968 he lead the Group respons...

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Format:HardcoverDimensions:528 pages, 9.69 × 6.73 × 1.31 inPublished:July 25, 2015Publisher:Oxford University PressLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0199695822

ISBN - 13:9780199695829

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Table of Contents

1. Setting the Scene2. MBE: the early history3. Machine technology4. Fundamentals5. Modifies growth techniques6. Low dimensional structures7. Nitrides, phosphides, antimonides and bismides8. II-VI and IV-VI compounds and Si/Ge9. Electronic devices10. Optical devices