Molecular Orbitals Of Transition Metal Complexes

Hardcover | March 24, 2005

byYves JeanTranslated byColin Translated by: Marsden

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This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions suchas symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure andthe geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifthchapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some ofthe complexes studied in the earlier chapters.

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This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions suchas symmetry, overlap and electronegativity, ...

Yves Jean is Professor at University Paris-Sud (Orsay, France) and Researcher at Ecole Polytechnique (Palaiseau, France).
Format:HardcoverDimensions:263 pages, 9.69 × 7.44 × 0.83 inPublished:March 24, 2005Publisher:Oxford University PressLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0198530935

ISBN - 13:9780198530930

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Table of Contents

1. Setting the scene2. Principal ligands fields: sigma interactions3. Pi-type interactions4. Applications5. The isolobal analogy6. Elements of group theory and applications

Editorial Reviews

`... excellent -- it covers both the foundations, necessary molecules, and interesting bonding puzzles.'R. Hoffmann, Cornell University, Nobel Laureate Chemistry 1981