Neutron Spin Echo Spectroscopy Viscoelasticity Rheology by B. EwenNeutron Spin Echo Spectroscopy Viscoelasticity Rheology by B. Ewen

Neutron Spin Echo Spectroscopy Viscoelasticity Rheology

byB. Ewen, M. Mours, D. Richter

Paperback | October 3, 2013

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Viscoelasticandtransportpropertiesofpolymersintheliquid(solution,melt)or liquid-like (rubber) state determine their processing and application to a large extent and are of basic physical interest [1-3]. An understanding of these dynamic properties at a molecular level, therefore, is of great importance. However,thisunderstandingiscomplicatedbythefactsthatdi?erentmotional processes may occur on di?erent length scales and that the dynamics are governed by universal chain properties as well as by the special chemical structure of the monomer units [4,5]. The earliest and simplest approach in this direction starts from Langevin equations with solutions comprising a spectrum of relaxation modes [1-4]. Special features are the incorporation of entropic forces (Rouse model, [6]) which relax uctuations of reduced entropy, and of hydrodynamic interactions (Zimm model, [7]) which couple segmental motions via long-range back ow elds in polymer solutions, and the inclusion of topological constraints or entanglements (reptation or tube model, [8-10]) which are mutually imposed within a dense ensemble of chains. Another approach, neglecting the details of the chemical structure and concentratingontheuniversalelementsofchainrelaxation,isbasedondynamic scalingconsiderations[4,11].Inparticularinpolymersolutions,thisapproach o?ers an elegant tool to specify the general trends of polymer dynamics, although it su?ers from the lack of a molecular interpretation. A real test of these theoretical approaches requires microscopic methods, which simultaneously give direct access to the space and time evolution of the segmental di?usion. Here, quasi-elastic scattering methods play a crucial role sincetheyallowthemeasurementofthecorrespondingcorrelationfunctions.In particular,thehigh-resolutionneutronspinecho(NSE)spectroscopy[12-15]is very suitable for such investigations since this method covers an appropriate range in time (0.005)t/ns)40) and space (r/nm [15). Furthermore, the possibilityoflabellingbyhydrogen-deuteriumexchangeallowstheobservation of single-chain behavior even in the melt.
Title:Neutron Spin Echo Spectroscopy Viscoelasticity RheologyFormat:PaperbackDimensions:248 pagesPublished:October 3, 2013Publisher:Springer-Verlag/Sci-Tech/TradeLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:366214803X

ISBN - 13:9783662148037


Table of Contents

Neutron Spin Echo Investigations on the Segmental Dynamics of Polymers in Melts, Networks and Solutions.- Deformation and Viscoelastic Behavior of Polymer Gels in Electric Fields.- Rheology of Polymers Near Liquid-Solid Transitions.