Organosilicon Compounds: From Theory To Synthesis To Applications

Paperback | August 1, 2017

byVladimir Ya Lee

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Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon-silicon bonds. This field, which includes compounds which are widely encountered in commercial products, such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last few years. Beginning with the theoretical aspects of organosilicon compounds structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, reactive intermediates, silaaromatics, multiple bonds to silicon, and more. Next, readers will find valuable sections that explore physical and chemical properties, X-ray crystallography, 29Si NMR spectroscopy, mass spectrometry, and other methods. Finally, the work delves into applications for industrial uses and in related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental theoretical, synthetic, physico-chemical and applied material science, applications aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers from both academia and industry Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

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Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon-silicon bonds. This field, which includes compounds which are widely encountered in commercial products, such as in the fabrication ...

Dr. Lee has more than 30 years in experimental organometallic chemistry, specializing in the field of Main Group elements chemistry, primarily the heavier Group 14 elements (Si, Ge, Sn, Pb). In addition to his background and career as a synthetic organometallic chemist, he has extensive experience of the scientific writing and publishi...

other books by Vladimir Ya Lee

Format:PaperbackDimensions:500 pages, 8.75 × 6.35 × 0.68 inPublished:August 1, 2017Publisher:Academic PressLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0128019816

ISBN - 13:9780128019818

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Table of Contents

I. Theory
Chapter I.1 Nonclassical Organosilicon Compounds
II. Experiment
II.1. Synthesis
II.1.1. Organosilicon Compounds of Tetracoordinate Silicon
Chapter II.1.1.1. Transition Metal Complexes of Silicon (excluding silylene complexes)
Chapter II.1.1.2. Silicon Cages and Clusters
Chapter II.1.1.3. Chiral Organosilicon Compounds
II.1.2. Organosilicon Compounds of Low-Coordinate Silicon
Chapter II.1.2.1. Silicon-Centered Cations
Chapter II.1.2.2. Silicon-Centered Radicals
Chapter II.1.2.3. Silicon-Centered Anions
Chapter II.1.2.4. Silylenes and Their Transition Metal Complexes
Chapter II.1.2.5. Multiple Bonds to Silicon
Chapter II.1.2.6. Silaaromatics and Related Compounds
II.1.3. Organosilicon Compounds of Hypercoordinate Silicon
Chapter II.1.3.1. Penta - and Hexacoordinated Silicon (IV) Compounds
II.2. Physico-Chemical Studies
Chapter II.2.1. X-Ray Crystallography of Organosilicon Compounds
Chapter II.2.2. 29Si NMR Spectroscopy
Chapter II.2.3. Thermochemistry of Organosilicon Compounds
Chapter II.2.4. Photoelectron Spectroscopy of Organosilicon Compounds
III. Applications
Chapter III.1. Hydrosilylation of the Carbon-Carbon Multiple Bonds
Chapter III.2. Polysilanes
Chapter III.3. Siloxanes and Silicones
Chapter III.4. Silicon-Based Dendrimers and Irregular Hyperbranched Polymers