Oxoacidity: reactions of oxo-compounds in ionic solvents by Victor L. CherginetsOxoacidity: reactions of oxo-compounds in ionic solvents by Victor L. Cherginets

Oxoacidity: reactions of oxo-compounds in ionic solvents

byVictor L. CherginetsEditorVictor L. Cherginets

Hardcover | June 9, 2005

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The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented.

This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry.



  • First book devoted to oxoacids and oxobases
  • Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena
  • The perfect handbook for beginners looking for preliminary knowledge about methods of investigation
Title:Oxoacidity: reactions of oxo-compounds in ionic solventsFormat:HardcoverDimensions:352 pages, 9.45 × 6.5 × 0.98 inPublished:June 9, 2005Publisher:Elsevier ScienceLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0444517820

ISBN - 13:9780444517821

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Table of Contents

Chapter 1. Homogeneous acid-base equilibria Part 1. Definitions of acids and bases Part 2. Studies of homogeneous acid-base reactions in ionic melts Part 3. Acid-base ranges in ionic melts Estimation of relative acidic properties of ionic melts

Chapter 2. Oxygen electrodes in ionic melts. Oxide ion donors Part 4. Oxygen electrode reversibility in ionic melts Part 5. Investigations of dissociation of Lux bases in ionic melts

Chapter 3. Equilibria in 'solid oxide-ionic melt' systems Part 6. Parameters describing oxide dissolution process and methods of their determination Part 7. Regularities of oxide solubilities in melts based on alkali and alkaline earth metal halides

Editorial Reviews

"This very valuable volume, which should be on the book shelves of all, working in chemistry and electrochemistry of molten salts. The theoretical concepts and wide range of experimental information collected in this book provides a solid basis not only to the basic, but also to the applied research, especially in the fields of chemical and electrochemical synthesis from molten salts, high-temperature chemical power sources, surface treatment of alloys, recycling of nuclear waster materials, etc." ELECTROCHIMICA ACTA 51 (2006)3181-3182. G. Kaptay, Department of Chemistry, University of Miskolc, Hungary