Synthetic Aspects

Other | March 1, 1995

byPage, Philip, Philip Page

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During the last few years, the impact of organosulfur chemistry, especially in the areas of stereocontrolled processes, has led to an explosion of interest in the field. This book is intended to provide in-depth coverage of topics of interest throughout the whole range of organic sulfur chemistry, including bio-organic, physical organic, and synthetic aspects.

This books covers such topics as:
Synthetic transformations involving thiiranium ion intermediates
Optically active (-ketosulfoxides and analogues in asymmetric synthesis
Trends in the chemistry of 1,3-dithioacetals

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From the Publisher

During the last few years, the impact of organosulfur chemistry, especially in the areas of stereocontrolled processes, has led to an explosion of interest in the field. This book is intended to provide in-depth coverage of topics of interest throughout the whole range of organic sulfur chemistry, including bio-organic, physical organi...

Format:OtherDimensions:277 pages, 1 × 1 × 1 inPublished:March 1, 1995Publisher:Academic PressLanguage:English

The following ISBNs are associated with this title:

ISBN - 10:0080538193

ISBN - 13:9780080538198

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Table of Contents

G. Solladie and M.C. Carreto,<_24_>Optically Active Beta-keto Sulfoxides and Analogues in Assymetric Synthesis.<_24_>Introduction. Homochiral Sulfoxide Preparations: the Andersen Approach. Stereoselective Reduction of Beta-keto Sulfoxides. Application of the Beta-keto Sulfoxide Reduction to Total Synthesis. Diels-Alder Reactions to Alkenyl Sulfoxides as Dienophiles. Diels-Alder Reactions of Sulfinyldienes.D. Crich,<_24_>Homolytic Processes at Sulfur in Synthesis.<_24_>Introduction. Reactions of Sulfur-Centered Radicals. Generations of Alkyl Radicals from Organosulfur Groups. Formation of Carbon-Sulfur Bonds by Reaction of Carbon-Centered Radicals with Sulfur Functional Groups.C.M. Rayner,<_24_>Synthetic Transformations Involving Thiiranium Ion Intermediates.<_24_>Reviews. General Considerations. Synthesis of Thiiranium Ion. Reactions of Thiiranium Ions. Summary.W.W. Wood,<_24_>Trends in the Chemistry of 1,3-Dithioacetals.<_24_>Introduction. Applications of Dithioacetals in Biological Effect Molecules. Synthesis of 1,3- Dithioacetals. Chemistry of 1,3- Dithioacetals. 1,3- Dithioacetal as a Functional Group.R. Okazaki,<_24_>Chemistry of Thioaldehydes.<_24_>Introduction. Transient Thioaldehydes. Stable Thioaldehydes.